If you want to enroll for Azure MFA the users need to go through these steps. When you enforce or enable MFA the user will be prompted for MFA enrollment. This is best done in a browser.

First the user need to access any of our endpoint e.g. http://portal.office.com

creds
Office 365 custom logo login

 

mfa prompt
Office 365 MFA enabled

 

input mfa method
Office 365 MFA input phone number

 

contact options
Office 365 mfa methods

 

 

sms
You will get a text message with a code to enter

 

wp_ss_20160902_0001
code on phone

 

Office 365 app password during enrollment
Use this app-password on your native iOS or Android device or old Outlook 2010 instead of your normal password.

 

 

Additional Office 365 MFA options
Press cancel if you feel done. or just navigate to the indended site. e.g. http://portal.office.com

 

Extended Office 365 MFA options
all your MFA options

 

Azure AD access panel for MFA
The user access panel

Here are all of the pictures in a Sway:
https://sway.com/2fNqmpbe5O17F5Ev

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